Essentially, a cut-free proof is a proof that does not use a lemma. That is

Given $(A\wedge B\wedge ...)\vdash C$, and $C\vdash (D\vee E\vee ...)$ we can cut $C$ from the proof of $(D\vee E\vee ...)$ when $(A\wedge B\wedge ...) $ is true. Here we consider $C$ to be the lemma in the proof of $(D\vee E\vee ...)$.

The ability to eliminate $C$ in the above is called the cut-elimination theorem. 

For more information set [http://en.wikipedia.org/wiki/Cut-elimination Cut-elimination]